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Diphosphorus tetraiodide : ウィキペディア英語版
Diphosphorus tetraiodide

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Diphosphorus tetraiodide is an orange crystalline solid with the formula P2I4. It has been used as a reducing agent in organic chemistry. It is a rare example of a compound with phosphorus in the +2 oxidation state, and can be classified as a subhalide of phosphorus. It is the most stable of the diphosphorus tetrahalides.
==Synthesis and structure==
Diphosphorus tetraiodide is easily generated by the disproportionation of phosphorus triiodide in dry ether:
:2 PI3 → P2I4 + I2
It can also be obtained by treating phosphorus trichloride and potassium iodide in anhydrous conditions.
The compound adopts a centrosymmetric structure with a P-P bond of 2.230 Å.〔Z. Žák, M. Černík "Diphosphorus tetraiodide at 120 K" Acta Crystallographica, Section C: Crystal Structure Communications 1996, vol. C52, pp. 290-1. 〕

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